KEAM – Engineering 2014 Examination Centre

 

Examination Centre
Thiruvananthapuram (TVM) Kollam (KLM)
Pathanamthitta (PTA) Alappuzha (ALP)
Kottayam (KTM) Ernakulam (EKM)
Idukki (IDK) Thrissur (TCR)
Palakkad (PKD) Malappuram (MLP)
Kozhikode (KKD) Wayanad (WYD)
Kannur (KNR) Kasaragod (KSD)
New Delhi (DLH) Dubai (DUB)

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KEAM – Engineering 2014 Scheme of the Examinations

  1.  The Entrance examination for Engineering streams will be objective type with Multiple Choice Questions and based on single response. For each question, five suggested answers would be given, of which only one will be the most appropriate response. The candidate will have to select and mark the alphabet (A,B,C,D or E) corresponding to the most appropriate response in the OMR Answer Sheet.
  2.  The question paper for objective type examinations will be given in the form of Question Booklets. Candidates will be permitted to take the question booklet with them at the end of examination.
  3.  For Engineering Entrance Examinations, each Paper will have 120 questions to be answered in 150 minutes.
  4.  Scoring, negative marks: For each correct response in the Engineering Entrance Examinations, the candidates will be awarded FOUR marks, and for each incorrect response, ONE mark will be deducted from the total score. For all these papers, in the event of failure to answer a question, (that is, no response is indicated against a question in the answer-sheet) no deduction from the total score will be made. More than one answer indicated against a question will be deemed as incorrect response, and will be awarded negative marks. Therefore the candidates are advised not to attempt an answer, if they are not sure of the response, because mere guessing may lead to choice of wrong answers, with the consequent penalty of negative marks. However, the candidates who fail to answer at least one question will be disqualified.

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KEAM – Engineering 2014 Eligibility

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KEAM – Engineering 2014 Exam Pattern

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KEAM – Engineering 2014 Examination Centre

 

KEAM – Engineering 2014 Online submission of Application

(a) The detailed instructions for filling each item in the application are given in  Prospectus and in the User Manual provided on the website www.cee-kerala.org
(b) There are 7 steps for the online submission of application and all the steps are mandatory. Candidates should complete all steps and should send the signed printout of the online submitted application along with the necessary certificates and documents on or before 9th February 2013. Candidate has to visit the website  www.cee.kerala.gov.in where he/she can find the link “KEAM-2014 Online Application”.

Step 1 : Candidate Registration

This is a one-time procedure. During the process candidates will get a system generated Application Number. Candidates are requested to enter their own password when
demanded. There will be a Security question and they should provide an answer to it. For further login, candidates have to note down all the information provided during this stage.

Step 2 : Candidate Login is required to proceed through all other stages of online submission. In order to login, candidate should provide Application number and Password.

Step 3 : Filling up of Application All the basic information, required at the Office of the Commissioner for Entrance Examinations are to be filled in at this step. Before filling the details, read the Prospectus carefully. The data provided here will be used for processing the application. Any mistake in filling this sheet or providing false/incomplete/wrong information will affect the candidate’s eligibility for admission or claim for reservation under any category. It is obligatory that the candidate
should fill all the items in the application. After filling the online application, candidate should click ‘Submit’ button to save the application. Before going to next stage (step 4), the candidate can login, view and modify the details provided here. Candidates should take utmost care while filling in the Online Application. Applicant should ensure that the data provided here are correct before proceeding to step 4.

Step 4 : Final Submission of Application This is also a one-time procedure. If candidate is sure that the information provided in step 3 is correct, click the link ‘Final Submission of Application’. Note that no modification of the application will be possible after doing this step.

Step 5 : Payment of Application Fee At this step candidate has to provide payment details of application fee.

Step 6 : Printout of the Application Candidate should take a printout of the online submitted application which contains all the information provided during step 3 and step 5. Candidates should get the Course Certificate and Nativity Certificate provided in the application.

Step 7 : Send the Printout of application and Supporting documents to Commissioner for Entrance Examinations Affix a passport size (3.5 x 3.5 cm) photograph of the applicant same as the photograph uploaded on the online application duly attested by the Head of the Institution which he/she studied last or by a Gazetted Officer. The applicant and parent should sign in the specified areas on the printout of the application and attach supporting documents/certificates and send to the Office of the Commissioner for Entrance Examinations, 5th Floor, Housing Board Buildings, Santhi Nagar, Thiruvananthapuram – 695 001 before the last date specified for submission of application.

(c) Applications should be complete in all respects. A candidate will be considered for the Entrance Examination or for admission, only if he/she has furnished the relevant certificates prescribed in the Prospectus, in proof of eligibility, or in support of any claim for reservation, under any category. The procedure of online submission of application will be complete only after the printout of Application and supporting documents / certificates are received in the office of the Commissioner for Entrance Examinations. Candidates are directed to keep a copy of completed application form for further reference.

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KEAM – Engineering 2014 Examination Centre

KEAM – Engineering 2014 Applying Process

Online Submission of Application : www.cee.kerala.gov.in . Online submission of application is required to apply for the Entrance Examination for admission. If a candidate submits more than one application his/her candidature is liable to be cancelled.

 Application Fee :

 A candidate who does not belong to SC/ST communities will be treated as ‘General’ candidate for the collection of application fee. The application fee for all candidates will be as follows:

General : Rs.700/-
SC / ST : Rs.350/-

 ST candidates whose annual family income is below Rs.40,000/- are exempted from payment of application fee on condition that they produce income certificate and caste certificate from the Revenue Authority.  who are children of Inter-Caste married couple of which one is SC/ST who will be eligible for educational and monetary benefits admissible to SC/ST , should mention the same in the form meant for it. They should attach an inter-caste marriage certificate from the Revenue officials along with the printout of the application form.

Candidates choosing ‘Dubai’ as Examination Centre will have to remit an additional fee of Rs.10,000/- by way of a Demand Draft (DD) drawn on a Nationalised Bank, in favour of the Commissioner for Entrance Examinations, payable at Thiruvananthapuram along with the application. Such candidates should give a local contact number, if available, in their application in the appropriate place. If the additional fee of Rs. 10,000/- is not paid by the candidates in the form of DD along with the application, they will be allotted a centre within the country.

 Candidates desirous of getting admission to Architecture Course and possessing the required minimum qualification will have to appear for the “National Aptitude Test in Architecture” (NATA), conducted by the National Institute for Advanced Studies in Architecture (NIASA). They should appear for NATA in such a manner that they can submit their NATA score . The details will be notified separately. Candidates applying for the Engineering  to appear for the ‘National Aptitude Test in Architecture’, as mentioned above.

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KEAM – Engineering 2014 Exam Dates

 

Paper I
Physics & Chemistry
21.04.2014 (Monday) 10 AM – 12.30 PM
Paper II
Mathematics
22.04.2014 (Tuesday) 10 AM – 12.30 PM

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KEAM – Engineering 2014 Admit Card

  1. The Admit Card for the Entrance Examination can be downloaded from the official website of the Commissioner for Entrance Examinations, www.cee.kerala.gov.in . The candidates will have to enter their Application number and Date of Birth provided in the application form in order to download the admit card. They will have to take a printout of the admit card. Admit cards will not be sent by post from the Office of the Commissioner for Entrance Examinations. Help Desks and Facilitation Centres will be functioning across the State from where candidates can download and take printouts of admit card. The venue of the examination and time table will be noted in the admit card. Separate notification in this regard will be issued.
  2.  Rejection memo will be sent to candidates whose application has been rejected. 
  3.  No memo will be sent by post in the case of defective applications. The defects in the applications will be displayed on the homepage of the candidate while attempting to download the admit card by giving his/her Application Number and Date of Birth. Defects if any, should be rectified within the dates specified in the notification pertaining to the download of admit cards.
  4.  All candidates whose application has been accepted should download their admit card well in advance. However there will be provision for those candidates who are unable to take a printout of the admit card to get an identification certificate through the concerned Liaison Officer .
  5.  The candidate himself/herself should meet the Liaison Officer with (i) his/her photograph attested on a plain paper by a Gazetted officer / the Head of the Institution where the candidate is studying or has studied and (ii) an identical photograph which has to be affixed in the Identification Certificate. Duplicate admit cards or Identification Certificates will not be issued to the candidates from the Office of the Commissioner for Entrance Examinations, directly.
  6.  A candidate who does not possess either the Admit Card or Identification Certificate issued by the Liaison Officer will not be admitted to the Examination Hall under any circumstances.

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KEAM – Engineering 2014 Introduction

  • Prospectus for Admission to Professional Degree Courses 2014, which has been approved by the Govt. of Kerala, is published herewith. It contains general information and rules relating to the Entrance Examinations for Admission to Professional Degree Courses 2014. Candidates are required to go through the Prospectus carefully and acquaint themselves with all the relevant information relating to the examinations/allotments. Candidates are also requested to visit the official website of the Commissioner for Entrance Examinations ‘www.cee-kerala.org’ regularly for notifications and announcements.
  •  This prospectus sets out the rules and regulations for selection and admission to the following professional degree courses conducted by the various authorities within the State of Kerala.
  •  Engineering Courses :

Bachelor of Technology (B.Tech.)
B.Tech. (Agricultural Engineering) [B.Tech. (Agri. Engg.)]
B.Tech. (Dairy Science & Technology) [B.Tech. (D.Sc. & Tech.)]
B.Tech. (Food Engineering) [B.Tech. (Food Engg.)]

  •  Admission to Engineering courses shall be regulated on the basis of merit as assessed by giving equal weightage of 50:50 to the marks obtained in the Entrance Examination for Engineering (Paper I & Paper II put together), and the grade/marks obtained for Mathematics, Physics and Chemistry put together in the final year of the qualifying examination, after effecting the standardization procedure as described. In case, the candidate has not studied Chemistry, the marks obtained in Computer Science shall be considered. In case, the candidate has not studied Chemistry and Computer Science, the marks obtained in Biotechnology shall be considered. In case, the candidate has not studied Chemistry, Computer Science and  Biotechnology , the marks obtained in Biology shall be considered. The marks as shown in the mark list obtained from the Board Examination of respective Higher Secondary Board shall be considered for academic eligibility.
  •  This Prospectus is subject to modification/addition/deletion, as may be deemed necessary by the Government.
  • Allotment of seats from the Rank Lists for all courses in Self-financing colleges will be made in accordance with the orders of the Hon’ble Supreme Court of India / Hon’ble High Court of Kerala or orders of the Govt. of Kerala/Govt. of India/as per the law in existence at the time of Centralised Allotment Process (CAP) and will be notified separately.

 COURSES, INSTITUTIONS AND SEATS

  •  Categorization of Seats in Government and Aided Institutions.
  •  Government seats : Merit seats against which the Commissioner for Entrance Examinations makes allotment are called ‘Government Seats’.
  •  Government seats are available in all the Govt. and Aided Colleges.
  •  The availability of Government seats in Self-financing Colleges run by institutions under Govt. control and other Private Self-financing colleges will be notified separately. Those candidates who seek admission in Private Self-financing colleges are bound to accept the conditions stipulated in the agreement between Government and Self-financing College Management(s) and deemed to have accepted such conditions.
  •  Management Seats are the seats set apart in the Aided institutions, to be filled up by the Managements concerned.
  •  Categorization of Seats in Self-Financing Institutions : The categorization of seats in Self-financing Colleges run by institutions under Govt. control and other Private Self-financing colleges will be notified separately.
  •  The B.Tech. Degree courses affiliated to various Universities in Kerala, under the semester scheme of studies comprise eight semesters.
  •  The B.Tech. (Agricultural Engineering) and the B.Tech. (Food Engineering) courses under the Kerala Agricultural University [KAU].
  • The B.Tech. (Dairy Science & Technology) course under the Kerala Veterinary and Animal Sciences University [KVASU].
  • Reservation of seats for Engineering Courses [B.Tech.]: The number of seats reserved for Government of India Nominees, Reciprocal quota and Special reservation categories.

Related links KEAM- Engineering 2014 :-

KEAM – Engineering 2014 Eligibility

KEAM – Engineering 2014 Syllabus

KEAM – Engineering 2014 Exam Pattern

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KEAM – Engineering 2014 Examination Centre

KEAM – Engineering 2014 Exam Pattern

Each question paper will have 4 versions as detailed below :

Paper I –  Physics & Chemistry Versions – A1, A2, A3 & A4.
Paper II – Mathematics Versions – B1, B2, B3 & B4.

Duration 150 Minutes
No of Questions 120
Maximum Marks 480

Scoring, negative marks: For each correct response in the Engineering Entrance Examinations, the candidates will be awarded FOUR marks, and for each incorrect response, ONE mark will be deducted from the total score. For all these papers, in the event of failure to answer a question, (that is, no response is indicated against a question in the answer-sheet) no deduction from the total score will be made. More than one answer indicated against a question will be deemed as incorrect response, and will be awarded negative marks. Therefore the candidates are advised not to attempt an answer, if they are not sure of the response, because mere guessing may lead to choice of wrong answers, with the consequent penalty of negative marks. However, the candidates who fail to answer at least one question will be disqualified.

Related links KEAM- Engineering 2014 :-

KEAM – Engineering 2014 Eligibility

KEAM – Engineering 2014 Syllabus

KEAM – Engineering 2014 Important Dates

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KEAM – Engineering 2014 Mathematics Syllabus

UNIT I: ALGEBRA

SETS, RELATIONS AND FUNCTIONS

Sets and their Representations: Finite and Infinite sets; Empty set; Equal sets; Subsets; Power set; Universal set; Venn Diagrams; Complement of a set; Operations on Sets (Union, Intersection and Difference of Set); Applications of sets: Ordered Pairs, Cartesian Product of Two sets; Relations: Domain, Co-domain and Range: Functions: into, on to, one – one in to, one-one on to Functions; Constant Function; Identity Function; composition of Functions; Invertible Functions; Binary Operations.

Complex Numbers

Complex Numbers in the form a + i b ; Real and Imaginary Parts of a complex Number; Complex Conjugate, Argand Diagram, Representation of Complex Number as a point in the plane; Modulus and Argument of a Complex Number; Algebra of Complex Numbers; Triangle Inequality; Polar Representation of a Complex Number.

Quadratic Equations

Solution of a Quadratic Equation in the Complex Number System by (i) Factorization (ii) Using Formula; Relation between Roots and Coefficients; Nature of Roots; Formation of Quadratic Equations with given Roots; Equations Reducible to Quadratic Forms.

Sequences and Series

Sequence and Examples of Finite and Infinite Sequences; Arithmetic Progression (A..P): First Term, Common Difference, nth Term and sum of n terms of an A.P.; Arithmetic Mean (A.M); Insertion of Arithmetic Means between any Two given Numbers; Geometric Progression (G.P): first Term, Common Ratio and nth term, Sum to n Terms, Geometric Mean (G.M); Insertion of Geometric Means between any two given Numbers.

Permutations, Combinations, Binomial Theorem and Mathematical Induction

Fundamental Principle of Counting; The Factorial Notation; Permutation as an Arrangement; Meaning of P(n, r); Combination: Meaning of C(n,r); Applications of Permutations and Combinations. Statement of Binomial Theorem; Proof of Binomial Theorem for positive integral Exponent using Principle of Mathematical Induction and also by combinatorial Method; General and Middle Terms in Binomial Expansions; Properties of Binomial Coefficients; Binomial Theorem for any Index (without proof); Application of Binomial Theorem. The Principle of Mathematical Induction, simple Applications.

Matrices and Determinants

Concept of a Matrix; Types of Matrices; Equality of Matrices (only real entries may be considered): Operations of Addition, Scalar Multiplication and Multiplication of Matrices; Statement of Important Results on operations of Matrices and their Verifications by Numerical Problem only; Determinant of a Square Matrix; Minors and Cofactors; singular and non-singular Matrices; Applications of Determinants in (i) finding the Area of a Triangle (ii) solving a system of Linear Equations (Cramer’s Rule); Transpose, Adjoint and Inverse of a Matrix; Consistency and Inconsistency of a system of Linear Equations; Solving System of Linear Equations in Two or Three variables using Inverse of a Matrix (only up to 3X3 Determinants and Matrices should be considered).

Linear Inequations

 Solutions of Linear Inequation in one variable and its Graphical Representation; solution of system of Linear Inequations in one variable; Graphical solutions of Linear inequations in two variables; solutions of system of Linear Inequations in two variables.

Mathematical Logic and Boolean Algebra

Statements; use of Venn Diagram in Logic; Negation Operation; Basic Logical Connectives and Compound Statements including their Negations.

UNIT II : TRIGONOMETRY

Trigonometric functions and Inverse Trigonometric functions

Degree measures and Radian measure of positive and negative angles; relation between degree measure and radian measure, definition of trigonometric functions with the help of a unit circle, periodic functions, concept of periodicity of trigonom etric functions, value of trigonometric functions of x for
x = 0, π/6, π / 4, π /3, π / 2, π , π, 3π /2 , 2 π ; trigonometric functions of sum and difference of numbers.

UNIT III: GEOMETRY

Cartesian System of Rectangular Co ordinates

Cartesian system of co ordinates in a plane, Distance formula, Centroid and incentre, Area of a triangle, condition for the collinearity of three points in a plane, Slope of line, parallel and perpendicular lines, intercepts of a line on the co ordinate axes, Locus and its equation.

Lines and Family of lines

Various forms of equations of a line parallel to axes, slope-intercept form, The Slope point form, Intercept form, Normal form, General form, Intersection of lines. Equation of bisectors of angle between two lines, Angles between two lines, condition for concurrency of three lines, Distance of a point from a line,
Equations of family of lines through the intersection of two lines.

Circles and Family of circles

Standard form of the equation of a circle General form of the equation of a circle, its radius and center, Equation of the circle in the parametric form.

Conic sections

Sections of a cone. Equations of conic sections [Parabola, Ellipse and Hyperbola] in standard form.

Vectors

Vectors and scalars, Magnitude and Direction of a vector, Types of vectors (Equal vectors, unit vector, Zero vector). Position vector of a point, Localized and free vectors, parallel and collinear vectors, Negative of a vector, components of a vector, Addition of vectors, multiplication of a vector by a scalar, position vector of point dividing a line segment in a given ratio, Application of vectors in geometry. Scalar product of two vectors, projection of a vector on a line, vector product of two vectors.

Three Dimensional Geometry

Coordinate axes and coordinate planes in three dimensional space, coordinate of a point in space, distance between two points, section formula, direction cosines, and direction ratios of a line joining two points, projection of the join of two points on a given line, Angle between two lines whose direction ratios are given, Cartesian and vector equation of a line through (i) a point and parallel to a given vector (ii) through two points, Collinearity of three points, coplanar and skew lines, Shortest distance between two lines, Condition for the intersection of two lines, Carterian and vector equation of a plane (i) When the normal vector and the distance of the plane from the origin is given (ii) passing though a point and perpendicular to a given vector (iii) Passing through a point and parallel to two given lines through the intersection of two other planes (iv) containing two lines (v) passing through three points, Angle between (i) two lines (ii) two planes (iii) a line and a plane, Condition of coplanarity of two lines in vector and Cartesian form, length of perpendicular of a point from a plane by both vector and Cartesian methods.

UNIT IV: STATISTICS

Statistics and probability

Mean deviation for ungrouped data, variance for grouped an ungrouped data, standard deviation. Random experiments and sample space, Events as subset of a sample space, occurrence of an event, sure and impossible events, Exhaustive events, Algebra of events, Meaning of equality likely outcomes, mutually exclusive events. Probability of an event; Theorems on probability; Addition rule, Multiplication rule, Independent experiments and events. Finding P (A or B), P (A and B), random variables, Probability distribution of a random variable.

UNIT V : CALCULUS

Functions, Limits and continuity

Concept of a real function; its domain and range; Modulus Function, Greatest integer function: Signum functions; Trigonometric functions and inverse trigonometric functions and their graphs; composite functions, Inverse of a function. Limits at Infinity and infinity limits; continuity of a function at a point, over an open/ closed interval; Sum, Product and quotient of continuous functions; Continuity of special functions- Polynomial, Trigonometric, exponential, Logarithmic and Inverse trigonometric functions.

Differentiation

Derivative of a function; its geometrical and physical significance; Relationship between continuity and differentiability; Derivatives of polynomial, basic    trigonometric , exponential, logarithmic and inverse trigonometric functions from first principles; derivatives of sum, difference, product and quotient of functions ; derivatives of polynomial, trigonometric, exponential, logarithmic, inverse trigonometric and implicit functions; Logarithmic differentiation; derivatives of functions expressed in parametric form; chain rule and differentiation by substitution; Derivatives of Second order.

Application of Derivatives

Rate of change of quantities; Tangents and Normals; increasing and decreasing functions and sign of the derivatives; maxima and minima; Greatest and least values; Rolle’s theorem and Mean value theorem; Approximation by differentials.

Indefinite Integrals

Integration as inverse of differentiation; properties of integrals; Integrals involving algebraic, trigonometric, exponential and logarithmic functions; Integration by substitution; Integration by parts;

Definite Integrals

Definite integral as limit of a sum; Fundamental theorems of integral calculus without proof); Evaluation of definite integrals by substitution and by using the following properties. Application of definite integrals in finding areas bounded by a curve, circle, parabola and ellipse in standard form between two ordinates and x-axis; Area between two curves, line and circle; line and parabola: line and ellipse.

Differential Equations

Definition; order and degree; general and particular solutions of a differential equation; formation of differential equations whose general solution is given; solution of differential equations by method of Separation of variables; Homogeneous differential equations of first order and their solutions; Solution of
linear differential equations of the type P(x) y Q(x).
Back to Syllabus

KEAM – Engineering 2014 Chemistry Syllabus

UNIT 1: BASIC CONCEPTS AND ATOMIC STRUCTURE

Laws of chemical combination: Law of conservation of mass. Law of definite proportion. Law of multiple proportions. Gay-Lussac’s law of combining volumes. Dalton’s atomic theory. Mole concept. Atomic, molecular and molar masses. Chemical equations. Balancing and calculation based on chemical equations.

 Atomic structure: Fundamental particles. Rutherford model of atom. Nature of electromagnetic radiation. Emission spectrum of hydrogen atom. Bohr model of hydrogen atom. Drawbacks of Bohr model. Dual nature of matter and radiation. de Broglie relation. Uncertainty principle. Wave function (mention only). Atomic orbitals and their shapes (s, p and d orbitals only). Quantum numbers. Electronic configurations of elements. Pauli’s exclusion principle. Hund’s rule. Aufbau principle.

UNIT 2: BONDING AND MOLECULAR STRUCTURE

Kossel and Lewis approach of bonding. Ionic bond, covalent character of ionic bond, Lattice energy.  Born-Haber cycle. Covalent bond. Lewis structure of covalent bond. Concept of orbital overlap. VSEPR theory and geometry of molecules. Polarity of covalent bond. Valence bond theory and hybridization (sp,sp, sp2 ,sp3,dsp2,d2sp3 and sp3d). Resonance. Molecular orbital method. Bond order. Molecular orbital diagrams of homodiatomic molecules. Bond strength and magnetic behaviour. Hydrogen bond. Coordinate bond. Metallic bond.

UNIT 3: STATES OF MATTER

Gaseous state: Boyle’s law. Charles’ law. Avogadro’s hypothesis. Graham’s law of diffusion. Absolute scale of temperature. Ideal gas equation. Gas constant and its values. Dalton’s law of partial pressure. Aqueous tension. Kinetic theory of gases. Deviation of real gases from ideal behaviour. Inter molecular interaction, van der Waals equation. Liquefaction of gases. Critical temperature.
Liquid state: Properties of liquids. Vapour pressure and boiling point. Surface tension. Viscosity.
Solid state: Types of solids (ionic, covalent and molecular). Space lattice and unit cells. Cubic crystal systems. Close packing. Different voids (tetrahedral and  octahedral only). Density calculations. Point defects (Frenkel and Schottky). Electrical properties of solids. Conductors, semiconductors and insulators. Piezoelectric and pyroelectric crystals. Magnetic properties of solids. Diamagnetic, paramagnetic, ferromagnetic, antiferromagnetic and ferrimagnetic substances.

UNIT 4: PERIODIC PROPERTIES OF ELEMENTS AND HYDROGEN

Classification of elements: Mendeleev’s periodic table. Atomic number and modern periodic law. Long form of periodic table. Electronic configurations of elements and their position in the periodic table. Classification into s-, p-, d- and f-block elements. Periodic properties: Ionization energy, electron affinity, atomic radii, valence and electro negativity.

Hydrogen: Position in the periodic table, occurrence, isolation, preparation (including commercial), properties, reactions and uses. Isotopes of hydrogen.

Hydrides: Molecular, saline and interstitial hydrides.

Water: Structure of water molecule and its aggregates. Physical and chemical properties of water. Hard and soft water. Removal of hardness. Preparation and uses of heavy water: Liquid hydrogen as fuel.

UNIT 5: S-BLOCK ELEMENTS AND PRINCIPLES OF METALLURGY

Alkali metals: Occurrence, electronic configuration, trends in atomic and physical properties (ionization energy, atomic radii and ionic radii), electrode potential, and reactions with oxygen, hydrogen, halogens and liquid ammonia. Oxides, hydroxides and halides.

Alkaline earth metals: Occurrence, electronic configuration, trends in atomic and physical properties, electrode potential, and reactions with oxygen, hydrogen and halogens. Oxides, hydroxides, halides and sulphides. Anomalous properties of lithium and beryllium.

Compounds of s-block elements: Large scale preparation of NaOH and Na2CO3, their properties and uses. Preparation and properties of CaO, Ca(OH)2, Plaster of Paris and MgSO4. Industrial uses of lime, limestone and cement.

Principles of metallurgy: Occurrence of metals. Concentration of ores. General principles of extraction of metals from ore. Thermodynamic and electro chemical principles of metallurgy. Refining of metals. Extraction of zinc, aluminium, iron and copper.

UNIT 6: P-BLOCK ELEMENTS

General characteristics of p-block elements: atomic and physical properties. Oxidation states. Trends in chemical reactivity of Groups 13, 14, 15, 16 and 17 elements.

Boron: Occurrence, isolation, physical and chemical properties. Borax and boric acid. Boron hydrides. Structure of diborane. Uses of boron and its compounds. Carbon: Allotropes, properties, Oxides of Carbon. Nitrogen: Terrestrial abundance and distribution, isolation, properties and chemical reactivity.

Ammonia: Haber process of manufacture, properties and uses. Nitric acid: Ostwald process of manufacture and important uses. Oxides of nitrogen: Preparation and structures (skeletal only).

Oxygen: Terrestrial abundance, isolation, properties and chemical reactivity.

Oxides: Acidic, basic and amphoteric oxides. Preparation, structure, properties and uses of ozone and hydrogen peroxide.

Silica: Different forms and uses. Structures of silicates. Silicones, Zeolites, Uses of Silicon Tetra Chloride.

Phosphorus: Production, allotropes and phosphine. Preparation and structures of PCl3, PCl5, oxyacids of phosphorus. Comparison of halides and hydrides of Group 15 elements. Sulphur: Production, allotropes, oxides and halides, Oxoacids of Sulphur (structure only).

Sulphuric acid: Manufacture, properties and uses. Comparison of oxides, halides and hydrides of Group 17 elements, Oxoacids of halogens (structure only), hydrides and oxides of chlorine. Interhalogen compounds.

Group 18 elements: Occurrence, isolation, atomic and physical properties, uses.

Compounds of xenon: Preparation of fluorides and oxides, and their reactions with water.

UNIT 7: D-BLOCK AND F-BLOCK ELEMENTS

d-Block elements: Electronic configuration and general characteristics. Metallic properties, ionization energy, electrode potential, oxidation states, ionic radii, catalytic properties, coloured ions, complex formation, magnetic properties, interstitial compounds and alloys. Preparation and properties of KMnO4, K2Cr2O7 .

f-Block elements: Lanthanides: Occurrence, electronic configuration and oxidation states. Lanthanide contraction. Uses.

Actinides: Occurrence, electronic configuration and comparison with lanthanides.

UNIT 8: THERMODYNAMICS

System and surrounding: Types of systems. Types of processes. Intensive and extensive properties. State functions and path functions. Reversible and irreversible processes.

First law of thermodynamics: Internal energy and enthalpy. Application of first law of thermodynamics. Enthalpy changes during phase transition. Enthalpy changes in chemical reactions. Standard enthalpy of formation. Hess’s law of constant heat summation and numerical problems. Heat capacity and specific heat.

Second law of thermodynamics: Entropy and Gibbs free energy. Free energy change and chemical equilibrium. Criteria for spontaneity.

UNIT 9: CHEMICAL EQUILIBRIUM

Physical and chemical equilibria: Dynamic nature of equilibrium. Equilibria involving physical changes (solid-liquid, liquid-gas, dissolution of solids in liquids and dissolution of gases in liquids). General characteristics of equilibria involving physical processes.

Equilibria involving chemical systems: Law of chemical equilibrium. Magnitude of equilibrium constant. Numerical problems. Effect of changing conditions of systems at equilibrium (changes of concentration, temperature and pressure). Effect of catalyst. The Le Chatelier principle and its applications. Relationship between Kp and Kc. Ionic equilibrium. Ionization of weak and strong electrolytes. Concepts of acids and bases: Those of Arrhenius, Bronsted-Lowry and Lewis. Acid-base equilibrium. Ionization of water. pH scale. Salt hydrolysis. Solubility product. Common ion effect. Buffer action and buffer solutions.

UNIT 10: SOLUTIONS

Types of solutions: Different concentration terms (normality, molarity, molality, mole fraction and mass percentage). Solubility of gases and solids. Vapour pressure of solutions and Raoult’s law. Deviation from Raoult’s law. Colligative properties: Lowering of vapour pressure, elevation in boiling point, depression in freezing point and osmotic pressure. Ideal and non-ideal solutions. Determination of molecular mass. Abnormal molecular mass. The van’t Hoff factor and related numerical problems.

UNIT 11: REDOX REACTIONS AND ELECTROCHEMISTRY

Oxidation and reduction: Electron transfer concept. Oxidation number.

Balancing equations of redox reactions: Oxidation number method and ion electron method (half reaction method).

Faraday’s laws of electrolysis: Quantitative aspects. Electrolytic conduction. Conductance. Molar conductance. Kohlrausch’s law and its applications. Electrode potential and electromotive force (e.m.f.). Reference electrode (SHE only). Electrolytic and Galvanic cells. Daniel cell. The Nernst equation. Free energy and e.m.f. Primary and secondary cells. Fuel cell (H2-O2 only).

Corrosion and its prevention: Electrochemical theory of rusting of iron. Methods of prevention of corrosion. Galvanization and cathodic protection.

UNIT 12: CHEMICAL KINETICS

Rate of reaction. Average and instantaneous rates. Rate expressions. Rate constant. Rate law. Order and molecularity. Integrated rate law expressions for zero and first order reactions and their derivations. Units of rate constant. Half life period. Temperature dependence of rate constant. Arrhenius equation. Activation energy, Collision Theory (Elementary theory) and related numerical problems. Elementary and complex reactions with examples.

UNIT 13: SURFACE CHEMISTRY

Adsorption: Physical and chemical adsorption. Factors affecting adsorption. Effect of pressure. Freundlisch adsorption isotherm. Catalysis. Enzymes.

Zeolites Colloids: Colloids and suspensions. Dispersion medium and dispersed phase.

Types of colloids: Lyophobic, lyophilic, multimolecular, macromolecular and associated colloids. Preparation, properties and protection of colloids. Gold number.
Hardy Schulze rule. Emulsions.

UNIT 14: COORDINATION COMPOUNDS AND ORGANOMETALLICS

Ligand. Coordination number. IUPAC nomenclature of coordination compounds mononuclear, Isomerism in coordination compounds. Geometrical, optical and  structural isomerism. Bonding in coordination compounds. Werner’s coordination theory. Valence bond approach. Hybridization and geometry. Magnetic properties of octahedral, tetrahedral and square planar complexes. Introduction to crystal field theory. Splitting of d orbitals in octahedral and tetrahedral fields (qualitative only). Importance of coordination compounds in qualitative analysis and biological systems such as chlorophyll, hemoglobin and vitamin B12 (structures not included).

UNIT 15: BASIC PRINCIPLES, PURIFICATION AND CHARACTERIZATION OF ORGANIC COMPOUNDS

Distinction between organic and inorganic compounds. Tetra valence of carbon. Catenation. Hybridization (sp, sp2  and sp3). Shapes of simple molecules. General introduction to naming of organic compounds. Trivial names and IUPAC nomenclature. Illustrations with examples. Structural isomerism. Examples of functional groups containing oxygen, hydrogen, sulphur and halogens.

Purification of carbon compounds: Filtration, crystallization, sublimation, distillation, differential extraction and chromatography (column and paper only).

Qualitative analysis: Detection of carbon, hydrogen, nitrogen and halogens.

Quantitative analysis: Estimation of carbon, hydrogen, nitrogen, sulphur, phosphorus and halogens (principles only), and related numerical problems. Calculation of empirical and molecular formulae.

UNIT 16: HYDROCARBONS

Classification of hydrocarbons. Alkanes and cycloalkanes: Nomenclature and conformation of ethane. 3D structures and 2D projections (Sawhorse and Newman). Alkenes and alkynes: Nomenclature. Geometrical isomerism in alkenes. Stability of alkenes. General methods of preparation. Physical and chemical properties. Markownikoff’s rule. Peroxide effect. Acidic character of alkynes. Polymerization reactions of dienes.

Aromatic hydrocarbons: Nomenclature. Isomerism. Benzene and its homologues. Structure of Benzene. Resonance. Delocalisation in benzene. Concept of aromaticity (an elementary idea). Chemical reactions of benzene. Polynuclear hydrocarbons and their toxicity.

UNIT 17: ORGANIC REACTION MECHANISM

Electronic displacement in a covalent bond: Inductive, electromeric, resonance and hyperconjugation effects. Fission of a covalent bond. Free radicals, electrophiles, nucleophiles, carbocations and carbanions.

Common types of organic reactions: Substitution, addition, elimination and rearrangement reactions. Illustrations with examples. Mechanism of electrophilic addition reactions in alkenes. Concept of delocalisation of electrons. Mechanism of electrophilic substitution reactions. Directive influence of substituents and their effect on reactivity (in benzene ring only).

UNIT 18: STEREOCHEMISTRY

Stereoisomerism: Geometrical isomerism and optical isomerism. Specific rotation. Chirality and chiral objects. Chiral molecules. Configuration and Fischer projections. Asymmetric carbon. Elements of symmetry. Compounds containing one chiral center. Enantiomers. Racemic form. Racemization. Compounds containing two chiral centers. Diastereo isomers. Meso form. Resolution.

UNIT 19: ORGANIC COMPOUNDS WITH FUNCTIONAL GROUPS CONTAINING HALOGENS

Haloalkanes and haloarenes: Nomenclature and general methods of preparation. Physical properties. Nature of C-X bond in haloalkanes and haloarenes. Chemical properties and uses of chloromethane and chlorobenzene. Polyhalogen compounds: Preparation and properties of chloroform and iodoform. Uses of some commercially important compounds (chloroform, iodoform, DDT, BHC and freon).

UNIT 20: ORGANIC COMPOUNDS WITH FUNCTIONAL GROUPS CONTAINING OXYGEN

Alcohols: Nomenclature. Important methods of preparation (from aldehydes, ketones, alkyl halides and hydration of alkenes). Manufacture of ethanol from molasses. Physical and chemical properties. Reactions with alkali metals and acids. Formation of alkenes, ethers and esters. Reactions with PX3, PX5, SOCl2. Oxidation of alcohols. Dehydrogenation.

Phenols: Nomenclature. Preparation of phenol (from sodium benzenesulphonate, benzene diazoniumchloride and chlorobenzene). Physical and chemical properties of phenol. Acidity of phenol. Action of phenol with FeCl3. Bromination, sulphonation and nitration of phenol.

Ethers: Nomenclature. Methods of preparation (from alcohols and alkyl halides). Williamson’s synthesis. Physical and chemical properties. Formation of peroxides. Actions with HI, HF and H2SO4. Some commercially important compounds: Methanol, ethanol (fermentation).

Aldehydes and ketones: Nomenclature. Electronic structure of carbonyl group. Methods of preparation (from alcohols, acid chlorides, ozonolysis of alkenes and hydration of alkynes). Friedel-Crafts acylation for acetophenone. General properties (physical and chemical) of aldehydes and ketones. Formation of paraldehyde and metaldehyde. Addition of NaHSO3, NH3 and its derivatives, Grignard reagent, HCN and alcohols. Oxidation reactions with Tollen’s reagent and Fehling’s solution. Oxidation of ketones. Reduction with LiAlH4. Clemmensen reduction. Wolff- Kischner reduction. Aldol condensation. Cannizzaro reaction.

Carboxylic acid: Nomenclature. Electronic structure of –COOH. Methods of Preparation (from alcohols, aldehydes, ketones, alkyl benzenes and hydrolysis of cyanide). Physical properties. Effects of substituents on acid strength. Chemical reactions.

UNIT 21: ORGANIC COMPOUNDS WITH FUNCTIONAL GROUPS CONTAINING NITROGEN

Amines: Nomenclature. Primary, secondary and tertiary amines. Methods of preparation. Physical properties. Basic nature. Chemical reaction. Separation of primary, secondary and tertiary amines. Cyanides and isocyanides. Diazonium salts. Preparation and chemical reactions of benzene diazoniumchloride in synthetic organic chemistry.

UNIT 22: POLYMERS AND BIOMOLECULES

Polymers: Classification. Addition and condensation polymerization. Copolymerization. Natural rubber and vulcanization. Synthetic rubbers. Condensation polymers. Biopolymers. Biodegradable polymers. Some commercially important polymers: Polyethene, polystyrene, PVC, Teflon, PAN, BUNA-N, BUNA-S, neoprene, Terylene, glyptal, nylon-6, nylon-66 and Bakelite.

Biomolecules: Classification of carbohydrates. Structure and properties of glucose. Reducing and nonreducing

sugars: Properties of sucrose, maltose and lactose (structures not included).

Polysaccharides: Properties of starch and cellulose. Proteins: Amino acids. Zwitterions. Peptide bond. Polypeptides. Primary, secondary and tertiary structures of protein. Denaturation of proteins. Enzymes. Nucleic acids. Types of nucleic acids. DNA and RNA, and their chemical composition. Primary structure of DNA. Double helix.

Vitamins: Classification and functions in biosystems.

UNIT 23: ENVIRONMENTAL CHEMISTRY AND CHEMISTRY IN EVERY DAY LIFE

Soil, water and air pollutions. Ozone layer. Smog. Acid rain. Green house effect and global warming. Industrial air pollution. Importance of green chemistry.
Chemicals in medicine and health care. Drug-target interaction, Analgesics, tranquillizers, antiseptics, antacids, antihistamines, antibiotics, disinfectants, antifertility drugs, chemicals in food, preservatives, artificial sweetening agents, antioxidants and edible colours, cleansing agents, soaps and synthetic detergents, antimicrobials.

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