LOYOLA COLLEGE (AUTONOMOUS), CHENNAI – 600 034
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M.Sc. DEGREE EXAMINATION – PHYSICS
FIRST SEMESTER – APRIL 2008
PH 1810 / 1801 – STATISTICAL MECHANICS
Date : 05/05/2008 Dept. No. Max. : 100 Marks
Time : 1:00 – 4:00
PART A ( 20 MARKS )
ANSWER ALL QUESTIONS. Each question carries 2 marks.
- State the ergodic hypothesis. Is it true ?
- Distinguish between the micro-canonical ensemble and the canonical ensemble.
- State the postulate of equal-a-priori probability.
- Sketch the Maxwell velocity distribution
- How does the vibrational contribution to the specific heat vary with temperature ?
- What are quasi-particles ? Give an example.
- What is the pressure exerted by an ideal Fermi gas at absolute zero ?
- What is the importance of the Chandrasekhar limit ?
- What is the implication of Einstein’s result for the energy fluctuations of blackbody radiation ?
- State Nyquist theorem.
PART B ( 30 MARKS )
ANSWER ANY FOUR QUESTIONS. Each question carries 7.5 marks.
- State and explain the basic postulates of statistical mechanics.
- Obtain the distribution for an ideal Maxwell –Boltzmann gas.
- Explain Bose-Einstein condensation. Discuss the super-fluidity of Helium by considering it as a form of Bose-Einstein condensation.
- Derive the Richardson-Dushman equation, which describes thermionic emission.
- Obtain the relations, which state the Wiener-Khintchine theorem.
PART C ( 50 MARKS )
ANSWER ANY FOUR QUESTIONS. EACH QUESTION CARRIES 12.5 MARKS.
- (a) Explain Gibb’s paradox. How is it resolved ?
(b) Prove Liouiville theorem.
- Calculate the entropy of an ideal Boltzmann gas using the micro canonical ensemble. Explain the corrections to be made to obtain the Sackur-Tetrode equation.
- Discuss the thermodynamic properties of an ideal Bose-Einstein gas.
- Calculate the pressure exerted by a Fermi-Dirac gas of relativistic electrons in the ground state. Use the result to explain the existence of the Chandrasekhar limit on the mass for a white dwarf.
- (a) Calculate the concentration fluctuations for a grand canonical ensemble. Show that for an ideal classical gas it increases as the volume of the gas increases.
(b) Prove the Nyquist theorem.
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