Loyola College Organic Chemical Technology Question Papers
Loyola College M.Sc. Chemistry April 2007 Organic Chemical Technology Question Paper PDF Download
LOYOLA COLLEGE (AUTONOMOUS), CHENNAI – 600 034
M.Sc. DEGREE EXAMINATION – CHEMISTRY
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FOURTH SEMESTER – APRIL 2007
CH 4955 – ORGANIC CHEMICAL TECHNOLOGY
Date & Time: 23/04/2007 / 9:00 – 12:00 Dept. No. Max. : 100 Marks
PART-A
Answer ALL questions. (10 ´ 2 = 20 marks)
- How is the formation of nitronium ion from nitration mixture detected and confirmed?
- How is the DVS ratio of a mixed acid calculated?
- Name some of the industrial oxidation reactions with examples.
- How are temperature controlled reactions performed industrially?
- How is spent acid from nitration reaction recycled?
- Define the following
- a) potential flow b) flash distillation
- What is boiling point diagram?
- Draw equilibrium diagram for C6H6-EtOH binary system.
- What is glycerin distillation and glycerin vaporization?
- What is roughness factor?
PART-B
Answer any EIGHT questions. (8 ´ 5 = 40 marks)
- Classify various chemical reactors and give a brief account on each.
- Write detailed notes on complex series reactions.
- Draw Hough nitrator and explain the method of preparation of mononitrobenzene from it.
- Give a detailed account on the design and material of reactors used for sulphonation.
- How various types of reactors built for halogenation reactions? Explain.
- Explain the preparation of a dye industrially?
- How will you calculate the vapour composition of a mixture in the distillation process using Raoult’s law?
- Discuss about the Hydrostatic equilibrium in a centrifugal field.
- Explain the working principle of centrifugal decanter for immiscible liquids.
- What are Newtonian and non-Newtonian fluids?
- What is Reynolds’s number? How the types flow is observed in Reynolds’s experiment?
- What is the pump work in Bernoulli’s equation?
PART-C
Answer any FOUR questions. (4 ´ 10 = 40 marks)
23 a) Compare batch reactor and longitudinal flow reactor for their performance and types of reactions.
- b) What is back mixing? Explain the effect of back mixing in consecutive reactions.
24 a) What are different types of nitrating agents? Explain the mechanism of each reaction.
- b) List out various workup procedures to isolate sulphonated products. Explain each one in detail.
- With a complete flow chart, explain the industrial preparation of penicillin.
- Explain about the total energy of steady flow process.
- Write note on types of impellers.
- Discuss the mechanical-energy balance in potential flow.
Loyola College M.Sc. Chemistry April 2008 Organic Chemical Technology Question Paper PDF Download
LOYOLA COLLEGE (AUTONOMOUS), CHENNAI – 600 034
|
M.Sc. DEGREE EXAMINATION – CHEMISTRY
FOURTH SEMESTER – APRIL 2008
CH 4955 – ORGANIC CHEMICAL TECHNOLOGY
Date : 25/04/2008 Dept. No. Max. : 100 Marks
Time : 9:00 – 12:00
PART – A
Answer ALL questions. (10 ´ 2 = 20 marks)
- What are the factors that affect the chemical-process kinetics?
- How is nitryl ion confirmed as the nitrating agent in aromatic nitration?
- Compare the sulphonating property of liquid SO3 and H2SO4.
- Write short note on the reactor materials used for various chemical reactions in industry.
- How is paracetamol prepared?
- What are Reynolds numbers? Give its significances.
- What is boiling point diagram?
- Mention the different streams involved in the transfer of heat and material across a plate.
- How leaching process is advantageous over washing and filtration process.
- What are the types of impellers? Give its applications.
PART – B
Answer any EIGHT questions. (8 ´ 5 = 40 marks)
- How are chemical reactors classified? Explain any three in detail.
- Write detailed notes on complex series reactions.
- Explain the effect of dilution in the formation of nitryl ion from acid mixture for aromatic nitration.
- Give a detailed account on the design and material of reactors used for sulphonation.
- Write short notes on various types of oxidising agents used industrially.
- Explain how penicillin is synthesized by industrial method.
- Explain hydrostatic equilibrium in a static fluid system.
- How immiscible liquids are separated by continuous gravity decanter?
- Define velocity gradient in a steady one-dimensional laminar flow.
- What is pump efficiency in Bernoulli equation?
- Explain the material balance of binary mixtures in the flash distillation process.
- Explain the working principle of spray dryers.
PART – C
Answer any FOUR questions. (4 ´ 10 = 40 marks)
- a) Explain the detailed synthesis of nitrobenzene using Hough nitrator. (8)
- b) How back mixing affects the product distribution in batch reactors? (2)
- a) What are the differences between fixed and fluidized bed catalytic reactors? Explain with examples. (5)
- b) List out various workup procedures to isolate sulphonated products. Explain each one in detail. (5)
- a) Write short notes on selection of suitable plant equipments. (4)
- b) Explain in detail the preparation of red and white pigments. (6)
- Derive an expression for the mechanical energy balance in potential flow and how the friction term is included in that expression.
- How the number of plates required for a distillation process is calculated by McCabe-Thiele method?
- Explain the working principle of the following
a) Flash dryer b) Bollman extractor.
Loyola College M.Sc. Chemistry April 2009 Organic Chemical Technology Question Paper PDF Download
LOYOLA COLLEGE (AUTONOMOUS), CHENNAI – 600 034
M.Sc. DEGREE EXAMINATION – CHEMISTRY
|
FOURTH SEMESTER – April 2009
CH 4955 – ORGANIC CHEMICAL TECHNOLOGY
Date & Time: 28/04/2009 / 9:00 – 12:00 Dept. No. Max. : 100 Marks
PART-A
Answer ALL questions. (10 ´ 2 = 20 marks)
- Define back mixing. What are its advantages and disadvantages?
- Why sulphonated products are very much useful industrially? Give reasons with example.
- What are the types of hydrogenating agents?
- Compare batch and parallel reactors.
- Narrate the preparation of titanium dioxide.
- A simple U-tube manometer is filled with mercury (specific gravity = 13.6) and the liquid above the mercury level is carbon tetrachloride (specific gravity = 1.6). The manometer reads 8.30 in. What is the pressure difference over the manometer in inches of water?
- What is Reynolds number? Give its significances.
- What is velocity gradient in a laminar flow?
- Define Couette flow.
- What is theoretical or equilibrium diagram?
PART-B
Answer any EIGHT questions. (8 ´ 5 = 40 marks)
- What are the physical factors that affect chemical process kinetics of chemical reactions? Write a short note on each.
- How is nitration of 2-methylpentane carried out? What are the products formed? Write the mechanism of the reaction.
- Explain in detail the workup procedure for sulphonation reaction and its products.
- How are various types of chlorination reactions performed industrially?
- What is the need for a research and development unit in industry? Discuss in detail.
- With the flow diagram explain the manufacture of paint.
- Describe the pump work in Bernoulli equation.
- Write short notes on impellers.
- Explain the working principle of bubble cap column with diagram.
- Explain the following
- a) energy balance over a flow system
- b) effect of temperature upon heat of the reaction
- Describe the various components involved in the fractionating column.
- What is differential distillation and give its applications?
PART-C
Answer any FOUR questions. (4 ´ 10 = 40 marks)
- a) Explain the effect of back-mixing on the product distribution and holding time in parallel and series reactions.
- b) How are temperature controlled reactions performed industrially?
- c) How is spent acid from nitration reaction recycled?
- a) Explain the method of nitration of hydrocarbons using Schmid nitrator.
- b) How is phenol manufactured industrially from cumene? Explain in detail.
- a) Explain the industrial preparation of hydrogenation of vegetable oil.
- b) What are the functions of quality control unit?
- a) Derive Barometric equation.
- b) Give the working principle of continuous gravity decanter.
- a) Explain the terms Newtonian and non-Newtonian flow.
- b) Write note on the mechanical energy balance in potential flow.
- How will you calculate the vapour composition of a mixture using Raoult’s law?
Loyola College M.Sc. Chemistry April 2011 Organic Chemical Technology Question Paper PDF Download
LOYOLA COLLEGE (AUTONOMOUS), CHENNAI – 600 034
M.Sc. DEGREE EXAMINATION – CHEMISTRY
FOURTH SEMESTER – APRIL 2011
CH 4955 – ORGANIC CHEMICAL TECHNOLOGY
Date : 09-04-2011 Dept. No. Max. : 100 Marks
Time : 9:00 – 12:00
PART-A
Answer ALL questions. (10 ´ 2 = 20 marks)
- Give the correlation between different temperature units.
- Define the term velocity gradient.
- Mention the advantages of inclined monometer over monometer.
- Define the following.
- a) extraction battery b) diffusion battery
- Compare the characteristics of distillation and extraction processes.
- How is the formation of nitronium ion from nitration mixture detected and confirmed?
- How is the DVS ratio of a mixed acid calculated?
- Why chlorination reaction is more important for industry?
- How are temperature controlled reactions performed industrially?
- How is spent acid from nitration reaction recycled?
PART-B
Answer any EIGHT questions. (8 ´ 5 = 40 marks)
- What are the standards of five basic SI units for mass, length, time, temperature, and mole?
- What are Newtonian and non-Newtonian fluids?
- Explain the working principle of centrifugal decanter for immiscible liquids.
- Derive an expression for the barometric equation.
- Explain the material balances in plate column with reference to two-component systems.
- Explain the working principle of moving-bed leaching machine.
- Classify various chemical reactors and give a brief account on each.
- Write detailed notes on complex series reactions.
- Draw Hough nitrator and explain the method of preparation of mononitrobenzene.
- Explain in detail the types of oxidizing agents used for industrial preparations.
- How various types of reactors built for halogenation reactions? Explain.
- Explain the preparation of a dye industrially?
PART-C
Answer any FOUR questions. (4 ´ 10 = 40 marks)
- Discuss the energy for single-stream process.
- a) Define the following
(i) Murphree efficiency (ii) Shank process - b) Explain the factors influencing plate efficiency.
- a) Explain the method of leaching by percolation through stationary solid beds.
- b) Write short notes on different types of impellers.
- a) Compare batch reactor and longitudinal flow reactor for their performance and types of reactions.
- b) What is back mixing? Explain the effect of back mixing in consecutive reactions.
- a) What are different types of nitrating agents? Explain the mechanism of each reaction.
- b) List out various workup procedures to isolate sulphonated products. Explain each one in detail.
- With a complete flow chart, explain the industrial preparation of penicillin.
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