syllabus for GCET engineering 2016

MATHEMATICS 

UNIT I: RELATIONS AND FUNCTIONS

1. Relations and Functions Types of relations: Reflexive, symmetric, transitive and equivalence relations. One to one and onto functions, composite functions, inverse
of a function. Binary operations. 2. Inverse Trigonometric Functions Definition, range, domain, principal value branches. Graphs of inverse trigonometric functions. Elementary properties of inverse trigonometric functions.

UNIT II: ALGEBRA

1. Matrices Concept, notation, order, equality, types of matrices, zero matrix, transpose of a matrix, symmetric and skew symmetric matrices. Addition,
multiplication and scalar multiplication of matrices, simple properties of addition, multiplication and scalar multiplication. Non-commutativity of multiplication of
matrices and existence of non-zero matrices whose product is the zero matrix (restrict to square matrices of order 2). Concept of elementary row and column
operations. Invertible matrices and proof of the uniqueness of inverse, if it exists; (Here all matrices will have real entries).
2. Determinants Determinant of a square matrix (up to 3 × 3 matrices), properties of determinants, minors, cofactors and applications of determinants in finding the area
of a triangle. Adjoint and inverse of a square matrix. Consistency, inconsistency and number of solutions of system of linear equations by examples, solving system of
linear equations in two or three variables (having unique solution) using inverse of a matrix.

UNIT III: CALCULUS

1. Continuity and Differentiability Continuity and differentiability, derivative of composite functions, chain rule, derivatives of inverse trigonometric functions,
derivative of implicit function. Concepts of exponential, logarithmic functions. PROSPECTUS FOR PROFESSIONAL DEGREE COURSES 2016-17 50
DIRECTORATE OF TECHNICAL EDUCATION, ALTO-PORVORIM, GOA, 403521 Derivatives of x e log and x e . Logarithmic differentiation. Derivative of functions
expressed in parametric forms. Second order derivatives. Rolle’s and Lagrange’s Mean Value Theorems (without proof) and their geometric interpretations
2. Applications of Derivatives Applications of derivatives: Rate of change, increasing/decreasing functions, tangents and normals, approximation, maxima and
minima (first derivative test motivated geometrically and second derivative test given as a provable tool). Simple problems (that illustrate basic principles and
understanding of the subject as well as real-life situations). 3. Integrals Integration as inverse process of differentiation. Integration of a variety of
functions by substitution, by partial fractions and by parts, only simple integrals of the type –

to be evaluated. Definite integrals as a limit of a sum. Fundamental Theorem of Calculus (without proof). Basic roperties of definite integrals and evaluation of definite integrals. 4. Applications of the Integrals Applications in finding the area under simple curves, especially lines, arcs of circles/parabolas/ellipses (in standard form only), area between the two above said curves (the region should be clearly identifiable).
5. Differential Equations Definition, order and degree, general and particular solutions of a differential equation. Formation of differential equation whose general solution is given. Solution of differential equations by method of separation of variables, homogeneous differential equations of first order and first degree.
Solutions of linear differential equation of the type –

UNIT IV: VECTORS AND THREE-DIMENSIONAL GEOMETRY

1. Vectors Vectors and scalars, magnitude and direction of a vector. Direction cosines/ratios of vectors. Types of vectors (equal, unit, zero, parallel and coplanar vectors), position vector of a point, negative of a vector, components of a vector, addition of vectors, multiplication of a vector by a scalar, position vector of a point dividing a line segment in a given ratio. Scalar (dot) product of vectors, projection of a vector on a line. Vector (cross) product of vectors, scalar triple product. 2. Three-dimensional Geometry Direction cosines/ratios of a line joining two points.
Cartesian and vector equation of a line, coplanar and skew lines, shortest distance between two lines. Cartesian and vector equation of a plane. Angle between (i) two lines, (ii) two planes, (iii) a line and a plane. Distance of a point from a plane.

UNIT V: LINEAR PROGRAMMING

Introduction, related terminology such as constraints, objective function, optimization, different types of linear programming (L.P.) problems, mathematical formulation of L.P. problems, graphical method of solution for problems in two variables, feasible and infeasible regions, feasible and infeasible solutions, optimal
feasible solutions (up to three non-trivial constraints).

UNIT VI: PROBABILITY

Multiplication theorem on probability. Conditional probability, independent events, total probability, Baye’s theorem. Random variable and its probability distribution, mean and variance of haphazard variable. Repeated independent (Bernoulli) trials and Binomial distribution.

CHEMISTRY

UNIT I: SOLID STATE

Classification of solids based on different binding forces :molecular, ionic covalent and metallic solids, amorphous and crystalline solids(elementary idea),unit cell in two dimensional and three
dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids ,number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic
properties, Band theory of metals ,conductors, semiconductors and insulators and n and p type semiconductors .

UNIT II : SOLUTIONS

Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in liquids, solid solutions, colligative properties – relative lowering of vapour pressure, Raoult’s law ,
elevation of B.P., depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties, abnormal molecular mass, Vant Hoff factor.

UNIT III: ELECTROCHEMISTRY

Redox reactions; conductance in electrolytic solutions, specific and molar  conductivity variations of conductivity with concentration, Kohlrausch’s Law, electrolysis and laws of electrolysis (elementary idea), dry cell – electrolytic cells and Galvanic cells; lead accumulator, EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells. Relation between Gibbs energy change and EMF of a cell, fuel cells; corrosion.

UNIT IV: CHEMICAL KINETICS

Rate of a reaction (average and instantaneous), factors affecting rates of reaction: concentration, temperature, catalyst; order and molecularity of a reaction; rate law and specific rate constant,
integrated rate equations and half life (only for zero and first order reactions); concept of collision theory (elementary idea, no mathematical treatment).Activation energy, Arrhenious equation.

UNIT V: SURFACE CHEMISTRY

Adsorption – physisorption and chemisorption; factors affecting adsorption of gases on solids; catalysis: homogenous and heterogeneous, activity and selectivity: enzyme catalysis; colloidal
state: distinction between true solutions, colloids and suspensions; lyophillic, lyophobic multimolecular and macromolecular colloids; properties of colloids; Tyndall effect, Brownian
movement, electrophoresis, coagulation; emulsions – types of emulsions.

UNIT VI: GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

Principles and methods of extraction – concentration, oxidation, reduction electrolytic method and refining; occurrence and principles of extraction of aluminium, copper, zinc and iron.

UNIT VII: P-BLOCK ELEMENTS

Group 15 elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties; nitrogen – preparation, properties and uses; compounds of nitrogen: preparation and properties of ammonia and nitric acid, oxides of nitrogen ( structure only); Phosphorous-allotropic forms; compounds of phosphorous: preparation and properties of phosphine, halides (PCl3 , PCl5 ) and oxoacids (elementary idea only). Group 16 elements : General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; dioxygen: preparation, properties and uses; classification of oxides; ozone. Sulphur – allotropic forms; compounds of sulphur: preparation, properties and uses of sulphur dioxide; sulphuric acid: industrial process of manufacture, properties and uses, oxoacids of sulphur (structures only). Group 17 elements : General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens: preparation, properties and uses of chlorine and hydrochloric acid, interhalogen compounds, oxoacids of halogens (structures only). Group 18 elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.

UNIT VIII: d AND f BLOCK ELEMENTS

General introduction ,electronic configuration, occurrence and characteristics of transition metals, general trends in properties of the first row transition metals – metallic character, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds, alloy formation. Preparation and properties of K2 Cr2 O7 and KMnO4 Lanthanoids – electronic configuration, oxidation states, chemical reactivity and  anthanoid contraction and its consequences. Actinoids – Electronic configuration, oxidation states and comparison with lanthenoids

UNIT IX: COORDINATION COMPOUNDS

Coordination compounds : Introduction, ligands, coordination number, colour, magnetic properties and shapes, IUPAC nomenclature of mononuclear coordination compounds, bonding, Werner’s
theory VBT,CFT; isomerism (structural and stereo)importance of coordination compounds (in qualitative analysis, extraction of metals and biological systems).

UNIT X: HALOALKANES AND HALOARENES

Haloalkanes: Nomenclature, nature of C-X bond, physical and chemical properties, mechanism of substitution reactions. Optical rotation.
Haloarenes: Nature of C-X bond, substitution reactions (directive influence of halogen for monosubstituted compounds only).
Uses and environmental effects of – dichloromethane, trichloromethane, tetrachloromethane, iodoform, freons, DDT.

UNIT XI: ALCOHOLS, PHENOLS AND ETHERS

Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary alcohols only); identification of primary, secondary and tertiary alcohols; mechanism of dehydration, uses, with special reference to methanol and ethanol. Phenols : Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophillic substitution reactions, uses of phenols. Ethers : Nomenclature, methods of  reparation, physical and chemical properties, uses.

UNIT XII: ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation,physical and chemical properties, and mechanism of nucleophilic addition, reactivity of alpha hydrogen in aldehydes; uses.
Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses.

UNIT XIII: ORGANIC COMPOUNDS CONTAINING NITROGEN

Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary secondary and tertiary amines. Cyanides and Isocyanides – will be mentioned at relevant places in context. Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.

UNIT XIV: BIOMOLECULES

Carbohydrates – Classification (aldoses and ketoses), monosaccharide (glucose and fructose), D-L
configuration, oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen): importance. Proteins – Elementary idea of a – amino acids, peptide bond, polypeptides, proteins, primary structure, secondary structure, tertiary structure and quaternary structure (qualitative idea only), denaturation of proteins; enzymes. Hormones –Elementary idea (excluding structure). Vitamins – Classification and functions. Nucleic Acids: DNA and RNA

UNIT XV: POLYMERS

Classification – Natural and synthetic, methods of polymerization (addition and condensation), copolymerization. Some important polymers: natural and synthetic like polythene, nylon, polyesters, bakelite, rubber. Biodegradable and non-biodegradable polymers.

UNIT XVI: CHEMISTRY IN EVERYDAY LIFE

1. Chemicals in medicines – analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamines.
2. Chemicals in food – preservatives, articial sweetening agents, elementary idea of antioxidants.
3. Cleansing agents – soaps and detergents, cleansing action.