LOYOLA COLLEGE (AUTONOMOUS), CHENNAI – 600 034
M.Sc. DEGREE EXAMINATION – CHEMISTRY
FOURTH SEMESTER – APRIL 2012
CH 4955 – ORGANIC CHEMICAL TECHNOLOGY
Date : 20-04-2012 Dept. No. Max. : 100 Marks
Time : 1.00 – 4.00
PART-A
Answer ALL questions: (10 ´ 2 = 20 marks)
- Mention any two rheological properties of fluids.
- What is inclined manometer? Give its advantages.
- Define the following.
- a) extraction battery b) diffusion battery
- Give the correlation between different temperature units.
- What is Couette flow?
- What are the factors affecting chemical process kinetics?
- How is the DVS ratio of a mixed acid calculated?
- What are mild hydrogenating catalysts? Why are they called so?
- Write all the products obtained when cumene hydrogenperoxide is hydrolysed?
- How is industrial bulk preparation different from fine chemicals?
PART-B
Answer any EIGHT questions: (8 ´ 5 = 40 marks)
- Explain the total energy balance of steady flow process.
- Derive barometric equation.
- Explain the working principle of concurrent leaching experiment.
- Write short notes on impellers.
- Discuss about the Hydrostatic equilibrium in a centrifugal field.
- Explain the various terminologies involved in the material balance diagram in plate column.
- Write the complete classification of various chemical reactors.
- Write detailed notes on parallel reactions and how is the product distribution affected due to back mixing?
- Explain the industrial chlorination of benzene. How are byproducts managed?
- Classify in detail the oxidizing agents used for industrial preparations.
- How is moisture control done to maintain proper DVS ratio during the industrial nitration of benzene?
- Explain the industrial preparation of a Hansa yellow dye.
PART-C
Answer any FOUR questions: (4 ´ 10 = 40 marks)
- a) Derive Bernoulli’s equation of flow of liquid in potential flow. (5)
- b) How the types of fluid flow identified by Reynolds experiment? (5)
- a) What is inclined manometer? Give its advantages. (4)
- b) Write notes on types of agitators and mixers. (6)
- a) Derive an expression for the overall material balance of distillation of two component system in a plate column. (5)
- b) Explain the working principle of tray dryer. (5)
- a) What are complex series reactions? Explain their importance. (5)
- b) How is nitration of benzene done using Biazzi nitrator? (5)
- a) Compare the reactivity of liquid SO3 and sulphuric acid towards sulphonation reactions. (4)
- b) Explain the industrial preparation of penicillin. (6)
- a) How is industrial scaling up done? (4)
- b) Write the preparation of blue and red pigments. (6)
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