PHYSICAL CHEMISTRY
Redox Reactions and Electrochemistry
Electronic concepts of oxidation and reduction, redox reactions, oxidation number, rules for assigning oxidation number, balancing of redox reactions.
Eectrolytic and metallic conduction, conductance in electrolytic solutions, specific and molar conductivities and their variation with concentration:
Kohlrausch’s law and its applications.
Electrochemical cells – Electrolytic and Galvanic cells, different types of electrodes, electrode potentials including standard electrode potential, half – cell and cell reactions, emf of a Galvanic cell and its measurement; Nernst equation and its applications; Relationship between cell potential and Gibbs’ energy change; Dry cell and lead accumulator; Fuel cells.
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