JEE Advanced Syllabus

JEE Main 2014 Syllabus Chemistry Unit -7

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PHYSICAL CHEMISTRY

Equilibrium

Meaning of equilibrium, concept of dynamic equilibrium.

Equilibria involving physical processes: Solid -liquid, liquid – gas and solid – gas

equilibria, Henry’s law, general characterics of equilibrium involving physical processes.

Equilibria involving chemical processes: Law of chemical equilibrium, equilibrium constants (Kp and Kc) and their significance, significance of DG and DGo in chemical equilibria, factors affecting equilibrium concentration, pressure, temperature, effect of catalyst; Le Chatelier’s principle.

Ionic equilibrium: Weak and strong electrolytes, ionization of electrolytes, various concepts of acids and bases (Arrhenius, Br??nsted – Lowry and Lewis) and their ionization, acid – base equilibria (including multistage ionization) and ionization constants, ionization of water, pH scale, common ion effect, hydrolysis of salts and pH of their solutions, solubility of sparingly soluble salts and solubility products, buffer solutions.

JEE Main 2014 Syllabus Chemistry Unit -6

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PHYSICAL CHEMISTRY

Solutions

Different methods for expressing concentration of solution – molality, molarity, mole fraction, percentage (by volume and mass both), vapour pressure of solutions and Raoult’s Law – Ideal and non-ideal solutions, vapour pressure – composition, plots for ideal and non-ideal solutions; Colligative properties of dilute solutions – relative lowering of vapour pressure, depression of freezing point, elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar mass, van’t Hoff factor and its significance.

JEE Main 2014 Syllabus Chemistry Unit -5

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PHYSICAL CHEMISTRY

Chemical Thermodynamics

Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes.

First law of thermodynamics – Concept of work, heat internal energy and enthalpy, heat capacity, molar heat capacity; Hess’s law of constant heat summation;

Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition, hydration, ionization and solution.

Second law of thermodynamics; Spontaneity of processes; DS of the universe and DG of the system as criteria for spontaneity, Dgo (Standard Gibbs energy change) and equilibrium constant.

JEE Main 2014 Syllabus Chemistry Unit -4

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PHYSICAL CHEMISTRY

Chemical bonding and Molecular Structure

Kossel – Lewis approach to chemical bond formation, concept of ionic and covalent bonds.

Ionic Bonding: Formation of ionic bonds, factors affecting the formation of ionic bonds; calculation of lattice enthalpy.

Covalent Bonding: Concept of electronegativity, Fajan’s rule, dipole moment; Valence Shell Electron Pair Repulsion (VSEPR) theory and shapes of simple molecules.

Quantum mechanical approach to covalent bonding:Valencebond theory – Its important features, concept of hybridization involving s, p and d orbitals;

Resonance.

Molecular Orbital Theory – Its important features, LCAOs, types of molecular orbitals (bonding, antibonding), sigma and pi-bonds, molecular orbital electronic configurations of homonuclear diatomic molecules, concept of bond order, bond length and bond energy.

Elementary idea of metallic bonding. Hydrogen bonding and its applications.

JEE Main 2014 Syllabus Chemistry Unit -3

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PHYSICAL CHEMISTRY

Atomic Structure

Thomson and Rutherford atomic models and their limitations; Nature of electromagnetic radiation, photoelectric effect; Spectrum of hydrogen atom, Bohr model of hydrogen atom – its postulates, derivation of the relations for energy of the electron and radii of the different orbits, limitations of Bohr’s model; Dual nature of matter, de-Broglie’s relationship, Heisenberg uncertainty principle. Elementary ideas of quantum mechanics, quantum mechanical model of atom, its important features, ?? and ??2, concept of atomic orbitals as one electron wave functions; Variation of ?? and ??2 with r for 1s and 2s orbitals; various quantum numbers (principal, angular momentum and magnetic quantum numbers) and their significance; shapes of s, p and d – orbitals, electron spin and spin quantum number; Rules for filling electrons in orbitals – aufbau principle, Pauli’s exclusion principle and Hund’s rule, electronic configuration of elements, extra stability of half-filled and completely filled orbitals.

JEE Main 2014 Syllabus Chemistry Unit -2

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PHYSICAL CHEMISTRY

 States of  Matter

Classification of matter into solid, liquid and gaseous states.

Gaseous State: Measurable properties of gases; Gas laws – Boyle’s law, Charle’s law, Graham’s law of diffusion, Avogadro’s law, Dalton’s law of partial pressure; Concept of Absolute scale of temperature; Ideal gas equation; Kinetic theory of gases (only postulates); Concept of average, root mean square and most probable velocities; Real gases, deviation from Ideal behaviour, compressibility factor and van der Waals equation.

LiquidState:

Properties of liquids – vapour pressure, viscosity and surface tension and effect of temperature on them (qualitative treatment only).

SolidState:

Classification of solids: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea); Bragg’s Law and its applications; Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell parameters, imperfection in solids; Electrical, magnetic and dielectric properties.

JEE Main 2014 Syllabus Chemistry Unit -1

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PHYSICAL CHEMISTRY

Some Basic Concepts in Chemistry

Matter and its nature, Dalton’s atomic theory; Concept of atom, molecule, element and compound; Physical quantities and their measurements in Chemistry, precision and accuracy, significant figures, S.I. Units, dimensional analysis; Laws of chemical combination; Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae; Chemical equations and stoichiometry.

JEE Main 2014 Syllabus Physics Unit – 21

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 EXPERIMENTAL SKILLS

Familiarity with the basic approach and observations of the experiments and activities:

1. Vernier callipers-its use to measure internal and external diameter and depth of a vessel.

2. Screw gauge-its use to determine thickness/diameter of thin sheet/wire.

3. Simple Pendulum-dissipation of energy by plotting a graph between square of amplitude and time.

4. Metre Scale – mass of a given object by principle of moments.

5. Young’s modulus of elasticity of the material of a metallic wire.

6. Surface tension of water by capillary rise and effect of detergents.

7. Co-efficient of Viscosity of a given viscous liquid by measuring terminal velocity of a given spherical body.

8. Plotting a cooling curve for the relationship between the temperature of a hot body and time.

9. Speed of sound in air at room temperature using a resonance tube.

10. Specific heat capacity of a given (i) solid and (ii) liquid by method of mixtures.

11. Resistivity of the material of a given wire using metre bridge.

12. Resistance of a given wire using Ohm’s law.

13. Potentiometer –

(i) Comparison of emf of two primary cells.

(ii) Determination of internal resistance of a cell.

14. Resistance and figure of merit of a galvanometer by half deflection method.

15. Focal length of:

(i) Convex mirror

(ii) Concave mirror, and

(iii) Convex lens

using parallax method.

16. Plot of angle of deviation vs angle of incidence for a triangular prism.

17. Refractive index of a glass slab using a travelling microscope.

18. Characteristic curves of a p-n junction diode in forward and reverse bias.

19. Characteristic curves of a Zener diode and finding reverse break down voltage.

20. Characteristic curves of a transistor and finding current gain and voltage gain.

21. Identification of Diode, LED, Transistor, IC, Resistor, Capacitor from mixed collection of such items.

22. Using multimeter to:

(i) Identify base of a transistor

(ii) Distinguish between npn and pnp type transistor

(iii) See the unidirectional flow of current in case of a diode and an LED.

(iv) Check the correctness or otherwise of a given electronic component (diode, transistor or IC).

JEE Main 2014 Syllabus Physics Unit – 20

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 COMMUNICATION SYSTEMS

Propagation of electromagnetic waves in the atmosphere; Sky and space wave propagation, Need for modulation, Amplitude and Frequency Modulation, Bandwidth of signals, Bandwidth of Transmission medium, Basic Elements of a Communication System (Block Diagram only).

JEE Main 2014 Syllabus Physics Unit – 19

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 ELECTRONIC DEVICES

Semiconductors; semiconductor diode: I-V characteristics in forward and reverse bias; diode as a rectifier; I-V characteristics of LED, photodiode, solar cell and Zener diode; Zener diode as a voltage regulator. Junction transistor, transistor action, characteristics of a transistor; transistor as an amplifier (common emitter configuration) and oscillator. Logic gates (OR, AND, NOT, NAND and NOR). Transistor as a switch.

JEE Main 2014 Syllabus Physics Unit – 18

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 ATOMS AND NUCLEI

Alpha-particle scattering experiment;Rutherford’s model of atom; Bohr model, energy levels, hydrogen spectrum. Composition and size of nucleus, atomic masses, isotopes, isobars; isotones. Radioactivity-alpha, beta and gamma particles/rays and their properties; radioactive decay law. Mass-energy relation, mass defect; binding energy per nucleon and its variation with mass number, nuclear fission and fusion.

JEE Main 2014 Syllabus Physics Unit – 17

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 DUAL NATURE OF MATTER AND RADIATION

Dual nature of radiation. Photoelectric ef fect , Hertz and Lenard’s observat ions; Einstein’s photoelectric equation; part icle nature of light . Matter waves-wave nature of part icle, de Broglie relation. Davisson-Germer experiment.

JEE Main 2014 Syllabus Physics Unit – 16

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 OPTICS

  • Reflection and refraction of light at plane and spherical surfaces, mirror formula, Total internal reflection and its applications, Deviation and Dispersion of light by a prism, Lens Formula, Magnification, Power of a Lens, Combination of thin lenses in contact, Microscope and Astronomical Telescope (reflecting and refracting) and their magnifyingpowers.
  • Wave optics: wavefront and Huygens’ principle, Laws of reflection and refraction using Huygen’s principle. Interference, Young’s double slit experiment and expression for fringe width. Diffraction due to a single slit, width of central maximum. Resolving power of microscopes and astronomical telescopes, Polarisation, plane polarized light; Brewster’s law, uses of plane polarized light and Polaroids.

JEE Main 2014 Syllabus Physics Unit – 15

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 ELECTROMAGNETIC WAVES

Electromagnetic waves and their characteristics. Transverse nature of electromagnetic waves. Electromagnetic spectrum (radio waves, microwaves, infrared, visible, ultraviolet, Xrays, gamma rays). Applications of e.m. waves.

JEE Main 2014 Syllabus Physics Unit – 14

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 ELECTROMAGNETIC INDUCTION AND ALTERNATING CURRENTS

Electromagnetic induction; Faraday’s law, induced emf and current; Lenz’s Law, Eddy currents. Self and mutual inductance. Alternating currents, peak and rms value of alternating current/ voltage; reactance and impedance; LCR series circuit, resonance; Quality factor, power in AC circuits, wattless current. AC generator and transformer.

JEE Main 2014 Syllabus Physics Unit – 13

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 MAGNETIC EFFECTS OF CURRENT AND MAGNETISM

  • Biot – Savart law and its application to current carrying circular loop. Ampere’s law and its applications to infinitely long current carrying straight wire and solenoid. Force on a moving charge in uniform magnetic and electric fields. Cyclotron.
  • Force on a current-carrying conductor in a uniform magnetic field. Force between two parallel current-carrying conductors-definition of ampere. Torque experienced by a current loop in uniform magnetic field; Moving coil galvanometer, its current sensitivity and conversion to ammeter and voltmeter.
  • Current loop as a magnetic dipole and  its magnetic dipole moment. Bar magnet as an equivalent solenoid, magnetic field lines; Earth’s magnetic field and magnetic elements.Para-, dia- and ferro- magnetic substances.
  • Magnetic susceptibility and permeability, Hysteresis, Electromagnets and permanent magnets.

JEE Main 2014 Syllabus Physics Unit – 12

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 CURRRENT ELECTRICITY

  • Electric current, Drift velocity, Ohm’s law, Electrical resistance, Resistances of different materials, V-I characteristics of Ohmic and nonohmic conductors, Electrical energy and power, Electrical resistivity, Colour code for resistors; Series and parallel combinations of resistors; Temperature dependence of resistance.
  • Electric Cell and its Internal resistance, potential difference and emf of a cell, combination of cells in series and in parallel. Kirchhoff’s laws and their applications. Wheatstone bridge, Metre bridge. Potentiometer – principle and its applications.

JEE Main 2014 Syllabus Physics Unit – 11

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 ELECTROSTATICS

  • Electric charges: Conservation of charge, Coulomb’s law-forces between two point charges, forces between multiple charges; superposition principle and continuous charge distribution.
  • Electric field: Electric field due to a point charge, Electric field lines, Electric dipole, Electric field due to a dipole, Torque on a dipole in a uniform electric field.
  • Electric flux, Gauss’s law and its applications to find field due to infinitely long uniformly charged straight wire, uniformly charged infinite plane sheet and uniformly charged thin spherical shell. Electric potential and its calculation for a point charge, electric dipole and system of charges; Equipotential surfaces, Electrical potential energy of a system of two point charges in an electrostatic field.
  • Conductors and insulators, Dielectrics and electric polarization, capacitor, combination of capacitors in series and in parallel, capacitance of a parallel plate capacitor with and without dielectric medium between the plates, Energy stored in a capacitor.

JEE Main 2014 Syllabus Physics Unit – 10

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 OSCILLATIONS AND WAVES

  • Periodic motion – period, frequency, displacement as a function of time. Periodic functions. Simple harmonic motion (S.H.M.) and its equation; phase; oscillations of a spring -restoring force and force constant; energy in S.H.M. – kinetic and potential energies; Simple pendulum – derivation of expression for its time period; Free, forced and damped oscillations, resonance.
  • Wave motion. Longitudinal and transverse waves, speed of a wave. Displacement relation for a progressive wave. Principle of superposition of waves, reflection of waves, Standing waves in strings and organ pipes, fundamental mode and harmonics, Beats, Doppler effect in sound.

JEE Main 2014 Syllabus Physics Unit – 9

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 KINETIC THEORY OF GASES

Equation of state of a perfect gas, work doneon compressing a gas.Kinetic theory of gases – assumptions, concept of pressure. Kinetic energy and temperature: rms speed of gas molecules; Degrees of freedom, Law of equipartition of energy,applications to specific heat capacities of gases; Mean free path, Avogadro’s number.

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